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Pre-chamber combustion (PCC) engines allow extending the lean limit of operation compared to common SI engines, thus being a candidate concept for the future clean transportation targets. To understand the fundamental mechanisms of the main chamber charge ignition in PCC engines, the effects of the composition in the pre-chamber were investigated numerically. A well-stirred reactor combustion model coupled with a methane oxidation mechanism reduced from GRI 3.0 was used. An open-cycle simulation was run with initialization at exhaust valve opening (EVO). For posterior simulations, the initial flow field was attained by mapping the field variables obtained from the full cycle simulation. The entire simulation domain (pre-chamber and main chamber) global excess air ratio (λ) was set to 1.3.